676683

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676683

Aldrich

 

(–)-9-(1R,2R-Pseudoephedrinyl)-(10S)-(trimethylsilyl)-9-borabicyclo[3.3.2]decane

Linear Formula:C22H38BNOSi
Molecular Weight:371.44
MDL number:MFCD09265095
PubChem Substance ID:24885324

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Description

ApplicationAir-stable, crystalline pseudoephedrine borinic acid complex which when treated with an appropriate Grignard reagent provides access to homoallylic or homopropargylic alcohols and α-allenyl carbinols.1,2,3

Properties

mp135-148 °C

Safety

Personal Protective Equipmentdust mask type N95 (US), Eyeshields, Gloves
Hazard CodesXi
Risk Statements36/37/38
Safety Statements26
WGK Germany3

References

Cited Reference1. J. Am. Chem. Soc. 127, 8044, (2005) Abstract
 2. Org. Lett. 7, 799, (2005) Abstract
 3. Org. Lett. 7, 5397, (2005) Abstract